Mass spectrometric investigation of the hydrogen-oxygen and methyl-oxygen reactions

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DOIResolve DOI: http://doi.org/10.1063/1.1742478
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TypeArticle
Journal titleThe Journal of Chemical Physics
ISSN0021-9606
Volume24
Issue2
Pages360364; # of pages: 5
AbstractThe reactions of hydrogen and of methyl radicals with oxygen have been studied by means of a mass spectrometer designed to detect free radicals. The reactants were present at low pressures in a stream of helium. Radicals detected were OH and HO2 in the hydrogen-oxygen reaction, and CH 3O, CH3O2, OH, HO2, CH2, and probably CHO in the methyl-oxygen reaction. A rough value of 10-3 to 10-4 was obtained for the collision efficiency of the oxygen+methyl radical reaction.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC)
Peer reviewedYes
NPARC number21276456
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Record identifier01a07aca-6cd6-483d-9ab8-3de46440da8d
Record created2015-10-13
Record modified2017-03-23
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