Vibrational spectroscopy of CO in gas-phase rhodium cluster-CO complexes

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DOIResolve DOI: http://doi.org/10.1021/ja036897s
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TypeArticle
Journal titleJournal of the American Chemical Society
ISSN00027863
Volume125
Issue37
Pages1118411185; # of pages: 2
AbstractInfrared spectra of isolated unsaturated rhodium cluster-CO complexes in the region of the CO stretching vibration, (CO), are measured using a molecular beam depletion technique. These spectra provide benchmarks for interpreting values of (CO) that are found when CO is used to probe Rh surfaces and supported Rh nanoparticles. Supported nanoparticles have shifts of (CO) of as much as +100 cm-1 compared to the free clusters measured here, indicative of significant charge transfer to the support.
Publication date
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedYes
Identifier10072378
NPARC number12329027
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Record identifier0b7a3b29-075e-447b-b2b5-619803dc587e
Record created2009-09-10
Record modified2016-05-09
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