Kinetic applications of electron paramagnetic resonance spectroscopy. XXI. Some mono-, di-, and trialkylhydrazyls

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DOIResolve DOI: http://doi.org/10.1021/ja00856a027
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TypeArticle
Journal titleJournal of the American Chemical Society
ISSN0002-7863
Volume97
Issue23
Pages67626766; # of pages: 5
AbstractThe kinetics, mechanism, and products of decay of some mono-, 1,2-di-, and trialkylhydrazyls have been examined. 1-Alkylhydrazyls decay with second-order kinetics at the diffusion-controlled limit, 1,2-Diisopropylhydrazyl undergoes a very rapid second-order decay, which is a β-disportionation to hydrazine and azo compound. According to their structure, trialkylhydrazyls may decay by a fast second-order β-disproportionation (alkyl-H → N) or by a slow ,β-scission (loss of alkyl and formation of an azo compound). These results, together with previously reported data on 2,2-diaikylhydrazyis, are discussed in relation to the possibilities of isolating persistent alkyl hydrazyl radicals.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC)
Peer reviewedYes
NPARC number21276717
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Record identifier0dbe0372-c9df-429c-ad22-05ccb0281da9
Record created2015-10-13
Record modified2016-05-09
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