Generalized Swain-Schaad relations including tunneling and temperature dependence

Download
  1. Get@NRC: Generalized Swain-Schaad relations including tunneling and temperature dependence (Opens in a new window)
AuthorSearch for: ; Search for:
TypeArticle
Journal titleChemical physics letters
ISSN0009-2614
Volume410
Issue4-6
Pages370376; # of pages: 7
AbstractThe Swain-Schaad relation, which relates the kinetic isotope effects of the three hydrogen isotopes, is extended by including tunneling and temperature dependence. The new version shows that the effect of tunneling on theSwain-Schaad exponent is opposite to that usually assumed and depends on the degree of assistance the tunneling receives from other vibrations.
Publication date
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
Identifier1020054x
NPARC number12328633
Export citationExport as RIS
Report a correctionReport a correction
Record identifier10dae693-de44-489b-a99a-fd59784dcc24
Record created2009-09-10
Record modified2016-05-09
Bookmark and share
  • Share this page with Facebook (Opens in a new window)
  • Share this page with Twitter (Opens in a new window)
  • Share this page with Google+ (Opens in a new window)
  • Share this page with Delicious (Opens in a new window)