A theoretical reexamination of carbanions adjacent to sulfoxide, sulfone and sulfonium centres

Download
  1. Get@NRC: A theoretical reexamination of carbanions adjacent to sulfoxide, sulfone and sulfonium centres (Opens in a new window)
DOIResolve DOI: http://doi.org/10.1016/S0040-4039(00)88264-7
AuthorSearch for: ; Search for: ; Search for:
TypeArticle
Journal titleTetrahedron Letters
Volume24
Issue38
Pages40714074; # of pages: 4
AbstractThe structures and proton affinities of CH2SR2 (R = H,CH3), -H2SOR (R = H,CH3) and -CH2SO2R (R = H,CH3) have been found at the 3-21G* (d-orbitals on sulfur) and 3-21G (no d-orbitals on sulfur) levels, using gradient optimization procedures. d-Orbital effects are important in these optimized structures. The factors leading to the structures now found, and the role of the d-orbitals, have been evaluated by quantitative PMO analyses of the wavefunctions.
Publication date
AffiliationNational Research Council Canada
Peer reviewedNo
NRC publication
This is a non-NRC publication

"Non-NRC publications" are publications authored by NRC employees prior to their employment by NRC.

NPARC number12328279
Export citationExport as RIS
Report a correctionReport a correction
Record identifier1a35f1fd-da97-4e3a-9d18-b3dfe764e65b
Record created2009-09-10
Record modified2016-05-09
Bookmark and share
  • Share this page with Facebook (Opens in a new window)
  • Share this page with Twitter (Opens in a new window)
  • Share this page with Google+ (Opens in a new window)
  • Share this page with Delicious (Opens in a new window)
Date modified: