Deuteration of cycloalkynes

  1. Get@NRC: Deuteration of cycloalkynes (Opens in a new window)
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Journal titleTetrahedron Letters
Pages34313432; # of pages: 2
AbstractWhen treated with the lithium salt of 1,3-diaminopropane, triple bonds in cyclic alkynes undergo multiple degenerate rearrangements. By employing the N,N,N′,N′-d4, reagent, the course of the isomerization is followed as the triple bond circumnavigates the ring. Cycloalkynes are readily perdeuterated with this novel methodology.
Publication date
AffiliationNRC Plant Biotechnology Institute; National Research Council Canada
Peer reviewedYes
NRC number24519
NPARC number21273773
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Record identifier27e4c873-f571-4051-a2fd-e9146f69465a
Record created2015-01-20
Record modified2016-05-09
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