Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

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DOIResolve DOI: http://doi.org/10.1039/c4cc02111h
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TypeArticle
Journal titleChemical Communications
ISSN1359-7345
Volume50
Issue78
Pages1147611479; # of pages: 4
Subjectcarbon; ionic clathrate hydrate; tetrabutylammonium; unclassified drug; chemical structure; crystal structure; encapsulation; molecular docking; nuclear magnetic resonance; proton nuclear magnetic resonance; X ray diffraction
AbstractWe report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO<inf>2</inf> molecules, which is found to provide high CO<inf>2</inf> storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.
Publication date
PublisherRoyal Society of Chemistry
LanguageEnglish
AffiliationNational Research Council Canada; Aerospace; Security and Disruptive Technologies
Peer reviewedYes
NPARC number21275603
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Record identifier2b7c2ef9-531e-418a-bfbc-9e9c66fd353f
Record created2015-07-14
Record modified2016-05-09
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