Kinetic applications of electron paramagnetic resonance spectroscopy. XXIV. Neophyl rearrangements

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DOIResolve DOI: http://doi.org/10.1021/ja00421a028
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TypeArticle
Journal titleJournal of the American Chemical Society
ISSN0002-7863
Volume98
Issue5
Pages12241226; # of pages: 3
AbstractThe rate constants for isomerization of 2-aryl-2-methylpropyl-1 to 1-aryl-2-methylpropyl-2 radicals have been measured by EPR spectroscopy over a range of temperatures. The radicals were derived by hydrogen abstraction from the following compounds: tert-butylbenzene, 1,3-di-tert-butylbenzene, 4-tert-butylpyridine, 2,6-di-tert-butylpyridine, and 2-tert-butylnaphthalene. The rates of isomerization of the radicals derived from the two pyridines and the naphthalene are significantly faster than the rates of isomerization of the radicals from the two benzenes.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC)
Peer reviewedYes
NPARC number21276700
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Record identifier2e349d17-0649-4ebe-88f7-b0986c9830ee
Record created2015-10-13
Record modified2016-05-09
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