New Approaches To Free Radical Thermochemistry [11

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DOIResolve DOI: http://doi.org/10.1163/187529786X00142
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TypeArticle
Journal titleReviews of Chemical Intermediates
Volume7
Issue1
Pages31-44(14)
AbstractA variety of unusual techniques have been used to measure thermodynamic propeties of free radicals and heats of the reactions in which they participate. These include a radical buffer EPR technique, the appearance energy method, photoacoustic spectroscopy, and electrochemical detection of free radicals. The methods can be applied to systems involving organometallic and high molecular weight materials which are normally inaccessible to conventional, gas phase techniques.
Publication date
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
NPARC number12339260
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Record identifier34be3b00-f4be-4a03-8030-631ec665247a
Record created2009-09-11
Record modified2016-05-09
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