Reactivity of Electrophilic Terminal Phosphinidene Complexes : P-P Bond Forming Reactions with Phosphines and Diphosphines

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DOIResolve DOI: http://doi.org/10.1021/om010640q
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TypeArticle
Journal titleOrganometallics
ISSN0276-7333
Volume20
Issue22
Pages44634465; # of pages: 3
AbstractReaction of the electrophilic phosphinidene complex [Cp*Mo(CO)3{PNiPr2}][AlCl4] with triethylphosphine results in reversible coordination of the phosphine to the phosphinidene phosphorus atom followed by carbonyl displacement at the metal. Phosphine-coordinated phosphinidene complexes with P-P bonds can be isolated by using diphosphines which coordinate first to the phosphinidene and then chelate to the phosphinidene and metal atoms.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
Identifier10309731
NPARC number12328922
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Record identifier359bead8-d47b-44ec-9de4-d50b49ac966c
Record created2009-09-10
Record modified2016-05-09
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