The Role of Alkoxyl Radicals in Gif (GoAggv) Chemistry

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DOIResolve DOI: http://doi.org/10.1016/0040-4039(95)02331-3
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TypeArticle
Journal titleTetrahedron Letters
ISSN0040-4039
Volume37
Issue6
Pages823826; # of pages: 4
Subjectketone; oxide; radical; article; catalysis; drug synthesis; reaction analysis
AbstractThe oxidation of cyclooctane using tert-alkyl hydroperoxides under GoAggv conditions has been examined using selected alkyl hydroperoxides as mechanistic probes. The results indicate that the products are formed by alkoxyl radical-induced reactions, there being no need to invoke any chemistry involving high valent iron-oxo species.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC)
Peer reviewedYes
NPARC number21276746
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Record identifier385b64db-97e8-4a18-a19b-b4b9f98464f5
Record created2015-10-13
Record modified2016-05-09
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