Polypseudorotaxane architecture of poly-bis[4-(N-benzyl- pyridinium)]piperazine-hexa-thiocyanato-di-cadmium(ii) with 2-D honeycomb-like [Cd(SCN)3]nn- anionic polymeric framework

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  1. Get@NRC: Polypseudorotaxane architecture of poly-bis[4-(N-benzyl- pyridinium)]piperazine-hexa-thiocyanato-di-cadmium(ii) with 2-D honeycomb-like [Cd(SCN)3]nn- anionic polymeric framework (Opens in a new window)
DOIResolve DOI: http://doi.org/10.1039/b701229b
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TypeArticle
Journal titleCrystEngComm
Volume9
Issue5
Pages345349; # of pages: 5
AbstractAn unusual, honeycomb-like cadmium-tri-thiocyanate polymeric framework was found in the studied hybrid material of general formula (L2+)n[Cd(SCN)3]2n2n-(3), where L2+ is bis[4-(N-benzylpyridinium)]piperazine dication. The perforated coordination net forms due to a template effect of the organic dications which reside in the holes penetrating the net in a polyrotaxane-like manner. The salt (L2+)(SCN)2[middle dot]2H2O (4) was studied for comparison.
Publication date
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
NPARC number12330195
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Record identifier3bda0c44-e3b9-4c2c-bb9f-3e26b05ad52d
Record created2009-09-10
Record modified2016-05-09
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