125Te NMR tomography of [Re6] cluster in Re6Te15 and related cluster compounds

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DOIResolve DOI: http://doi.org/10.1016/j.ssnmr.2003.05.004
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TypeArticle
Journal titleSolid State Nuclear Magnetic Resonance
Volume25
Issue1-3
Pages7275; # of pages: 4
Subjectchalkogenide compounds; Jahn-Teller effect; metal cluster; tomography of nano-particles
AbstractThe static and magic angle spinning NMR solid-state spectra of Re6Te15 and a series of Re6-Te cluster compounds demonstrate the positive and negative 125Te NMR chemical shifts indicating that the [Re6] cluster distorts strongly magnetic field at the neighboring Te sites. The local magnetic field is decreased at the facial tellurium sites (Teface) and enhanced at the apexial tellurium sites (Teapex). The facial and sagittal sections of the Re6-Te clusters were reconstructed from analysis of Teface and Teapex NMR spectra, respectively.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
NPARC number12328723
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Record identifier439e376d-6a8e-4d72-b0e0-12d2379fc803
Record created2009-09-10
Record modified2016-05-09
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