Supramolecular stabilization of hydroxylamine TEMPOH by complexation with an amphiphilic calixarene

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DOIResolve DOI: http://doi.org/10.1039/B511810G
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TypeArticle
Journal titleChemical Communications (Cambridge, England)
ISSN1359-7345
Issue4
Pages386–; # of pages: 388
SubjectCalixarenes; Cyclic N-Oxides; Free Radicals; Hexanols; Hydrogen; Hydrogen Bonding; Hydroxylamine; Models, Molecular; Nitrogen Oxides; Phenols; Temperature
AbstractIn an ethanol/water mixture, the nitroxyl radical TEMPO abstracts a hydrogen atom from a phenolic OH group of the amphiphilic para-hexanoylcalix[4]arene, and the hydroxylamine TEMPOH formed yields a stable inclusion complex with another molecule of the calixarene.
Publication date
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
Identifier10534386
NPARC number12338333
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Record identifier44e59e76-5621-4036-817f-d150f2f8fc05
Record created2009-09-10
Record modified2016-05-09
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