Geometries and excited-state dynamics of van der Waals dimers and higher clusters of 1-cyanonaphthalene

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DOIResolve DOI: http://doi.org/10.1063/1.2141613
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TypeArticle
Journal titleThe Journal Of Chemical Physics
ISSN00219606
Volume123
Issue24
Pages244306–; # of pages: 1
AbstractMass-selected resonant two-photon ionization and infrared-ultraviolet double-resonance spectroscopies are combined with correlated (second Moller-Plesset perturbation) quantum chemistry calculation to probe electronic spectra and ground-state geometries of the jet-cooled dimer and higher clusters of 1-cyanonaphthalene. The results indicate that the dimer and trimer have stacked geometries, consistent with the highly efficient, rapid excimer formation that follows photoexcitation of the ground-state clusters.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedYes
Identifier10012680
NPARC number12329102
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Record identifier456b47e6-6961-4e8f-9cb3-a38916c184a9
Record created2009-09-10
Record modified2017-03-23
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