Energy partitioning in O(1 D 2) reactions. II. O(1 D 2)+CH4 → OH(v’)+CH3

Download
  1. Get@NRC: Energy partitioning in O(1 D 2) reactions. II. O(1 D 2)+CH4 → OH(v’)+CH3 (Opens in a new window)
DOIResolve DOI: http://doi.org/10.1063/1.450571
AuthorSearch for: ; Search for: ; Search for:
TypeArticle
Journal titleThe Journal of Chemical Physics
ISSN0021-9606
Volume84
Issue2
Pages745749; # of pages: 5
SubjectEmission spectroscopy
AbstractThe complete OH vibrational distribution created by the reaction of O(1 D 2) with CH4 has been recorded directly, using low pressure infrared emission spectroscopy. The result shows that the energy is partitioned nonstatistically into this degree of freedom. The population of OH(v’=2) is approximately equal to or slightly greater than that of OH(v’=1) under the conditions of this experiment and substantial populations are recorded from all levels up to OH(v’=4), the maximum allowed by the exoergicity of the reaction.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada
Peer reviewedYes
NRC number24329
NPARC number21275075
Export citationExport as RIS
Report a correctionReport a correction
Record identifier4804f4c3-6115-4ba7-b020-befbac43681d
Record created2015-05-06
Record modified2017-03-23
Bookmark and share
  • Share this page with Facebook (Opens in a new window)
  • Share this page with Twitter (Opens in a new window)
  • Share this page with Google+ (Opens in a new window)
  • Share this page with Delicious (Opens in a new window)