Photochemistry of reaction intermediates

Download
  1. (PDF, 745 KB)
  2. Get@NRC: Photochemistry of reaction intermediates (Opens in a new window)
DOIResolve DOI: http://doi.org/10.1351/pac198658091273
AuthorSearch for: ; Search for:
TypeArticle
Journal titlePure and Applied Chemistry
ISSN0033-4545
1365-3075
Volume58
Issue9
Pages12731278; # of pages: 6
AbstractThe mechanisms and kinetics of the photochemistry of organic reaction intermediates have been examined using two—laser excitation techniques, and are illustrated using examples involving naphthalene chromophores. For example, excited 1—naphthylmethyl radicals are excellent electron donors, but not very good acceptors. They abstract halogens efficiently and interact with oxygen 5.5 times faster than their ground state. Other examples include the triplet states of 1,3—dinaph— thyipropanone, 1,2—dinaphthylethane and acenaphthene.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada; NRC Institute for Chemical Process and Environmental Technology
Peer reviewedYes
NRC numberNRC-
NPARC number21272088
Export citationExport as RIS
Report a correctionReport a correction
Record identifier4e6eb8ff-07ac-43e5-9f93-63c612e6c06c
Record created2014-07-15
Record modified2016-05-09
Bookmark and share
  • Share this page with Facebook (Opens in a new window)
  • Share this page with Twitter (Opens in a new window)
  • Share this page with Google+ (Opens in a new window)
  • Share this page with Delicious (Opens in a new window)