Observation of the "missing" polar OCS dimer

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DOIResolve DOI: http://doi.org/10.1063/1.2709879
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TypeArticle
Journal titleThe Journal Of Chemical Physics
Volume126
Issue7
Pages071102-1071102-3; # of pages: 3
Subjectcarbon compounds; infrared spectra; isomerism; microwave spectra; oxygen compounds
AbstractA new infrared band at 2069.3 cm-1 is observed and assigned to the long-anticipated polar isomer of the OCS dimer, helping to explain apparent discrepancies among earlier studies. The data reported here should enable direct observation of the microwave spectrum of polar (OCS)2 and motivate new theoretical works on the energetics of OCS dimer isomers and interconversion energy barriers.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedYes
NPARC number12327937
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Record identifier5004636c-65ed-483b-aef0-e843a0318483
Record created2009-09-10
Record modified2017-03-23
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