On the ν12 band of C6D6 at 2289 cm -1

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DOIResolve DOI: http://doi.org/10.1016/j.jms.2013.12.001
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TypeArticle
Journal titleJournal of Molecular Spectroscopy
ISSN0022-2852
Volume296
Pages1416; # of pages: 3
SubjectCombination bands; Fermi interaction; Infrared spectrum; Supersonic jets; Benzene; Molecular spectroscopy; Physical chemistry; Spectroscopy; Supersonic aerodynamics
AbstractNew supersonic jet spectra (T ≈ 2.5 K) show that the analysis by Plíva et al. (1994) of the ν12 (C-D stretch) band of C 6D6 near 2289 cm-1 is partly incorrect. In particular, the ν2 + ν13 combination band, which is strongly coupled to ν12 by a Fermi interaction, is centered at 2275.878 cm-1, which is 1.22 cm-1 higher than previously determined. © 2013 Elsevier Inc. All rights reserved.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC)
Peer reviewedYes
NPARC number21270835
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Record identifier5aecd89d-563e-42ac-848a-493efb770723
Record created2014-02-17
Record modified2016-05-09
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