A Putative Monooxygenase Mimic Which Functions via Well-Disguised Free Radical Chemistry

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DOIResolve DOI: http://doi.org/10.1021/ja963627j
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TypeArticle
Journal titleJACS: Journal of the American Chemical Society
ISSN0002-7863
Volume119
Issue44
Pages1059410598; # of pages: 5
AbstractThe hydroxylation of cycloalkanes at 25 C by the syringe pump addition of tert-alkyl hydroperoxides (10 and 1 equiv based on catalyst) to deoxygenated acetonitrile containing cycloalkanes (0.64 M) and 0.61 mM of the catalyst, [FeIII2O(TPA)2(H2O)2]4+, is demonstrated to be a reaction which involves freely diffusing cycloalkyl radicals, i.e., free alkyl radicals.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedYes
Identifier10072378
NPARC number12337874
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Record identifier5cf34322-5e32-4acc-a23b-1d901db3d29e
Record created2009-09-10
Record modified2017-03-17
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