The First Nonlayered Metal Sulfonate Structure: a 1-D Ba2+ Network Incorporating Hydrophobic Channels

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DOIResolve DOI: http://doi.org/10.1021/ic000733k
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TypeArticle
Journal titleInorganic Chemistry
ISSN0020-1669
Volume40
Issue4
Pages582583; # of pages: 2
AbstractThe single-crystal X-ray structure of the first nonlayered metal sulfonate has been determined. Barium 2-pyridylethanesulfonate forms a one-dimensional framework with a backbone of SO3- and H2O-bridged Ba2+ columns. Pendant to these columns are 6-fold divergent organic groups that define hydrophobic channels (7.7 × 9.1 Å) and include guest ethyl acetate molecules. Thermal analysis results are also presented.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
Identifier10007817
NPARC number12338890
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Record identifier60154343-ad5f-47b6-94de-406d1d100e53
Record created2009-09-11
Record modified2016-05-09
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