High-resolution synchrotron infrared spectroscopy of thiophosgene: The ν2 and ν4 fundamental bands near 500 cm−1

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DOIResolve DOI: http://doi.org/10.1016/j.jms.2009.12.004
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TypeArticle
Journal titleJournal of Molecular Spectroscopy
ISSN0022-2852
Volume260
Issue1
Pages6671; # of pages: 6
SubjectThiophosgene; Infrared; Synchrotron
AbstractThiophosgene (Cl2CS) is a favorite model system for studies of photophysics, vibrational dynamics, and intersystem interaction effects. But there are no previous rotationally-resolved infrared studies because the spectra are very congested due to hot bands and multiple isotopic species. This paper reports a detailed study of the ν2 (not, vert, similar504 cm−1) and ν4 (not, vert, similar471 cm−1) fundamental bands for the two most abundant isotopomers, 35Cl2CS and 35Cl37ClCS, based on spectra with observed line widths of not, vert, similar0.0008 cm−1 obtained at the Canadian Light Source far-infrared beamline using synchrotron radiation and a Bruker IFS125 Fourier transform spectrometer.
Publication date
LanguageEnglish
AffiliationNRC Steacie Institute for Molecular Sciences; National Research Council Canada
Peer reviewedYes
NPARC number17653062
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Record identifier6a0bad41-9479-48af-a83f-f7fd556992bc
Record created2011-03-31
Record modified2016-05-09
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