Time-resolved UV-visible spectroelectrochemistry using transparent 3D-mesoporous nanocrystalline ITO electrodes

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DOIResolve DOI: http://doi.org/10.1039/c0cc04154h
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TypeArticle
Journal titleChemical Communications
ISSN1359-7345
Volume47
Issue6
Pages18631865; # of pages: 3
Subjectcrystallin; indium tin oxide; microperoxidase 11; nanocrystal; peroxidase; unclassified drug; adsorption; article; cyclic potentiometry; electrochemistry; electrode; electron transport; enzyme immobilization; film; ionic strength; kinetics; molecule; oxidation reduction reaction; particle size; porosity; ultraviolet spectroscopy; Adsorption; Electrochemistry; Electrodes; Electron Transport; Microscopy, Electron, Scanning; Oxidation-Reduction; Peroxidases; Porosity; Spectrophotometry, Ultraviolet; Time Factors; Tin Compounds
AbstractEfficient and rapid adsorption of microperoxidase 11 within a highly porous ITO thin film (200 nm) prepared by glancing angle deposition was achieved. Adsorbed redox molecules were reversibly and rapidly reduced throughout the 3D-conductive matrix in ca. 50 ms, allowing the heterogeneous electron transfer rate to be determined by derivative cyclic voltabsorptometry. © 2011 The Royal Society of Chemistry.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC); National Institute for Nanotechnology (NINT-INNT)
Peer reviewedYes
NPARC number21271081
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Record identifier6d99fc97-5741-4307-9ff1-823417cc419c
Record created2014-03-24
Record modified2016-05-09
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