The synthesis of 2,3,4,6,7-penta-O-methyl-d-glycero-l-manno-heptose and 2,4,6,7-tetra-O-methyl-d-glycero-l-manno-heptose

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DOIResolve DOI: http://doi.org/10.1016/S0008-6215(00)80104-4
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TypeArticle
Journal titleCarbohydrate Research
ISSN0008-6215
Volume12
Issue2
Pages261266; # of pages: 6
Abstract2,3,4,6,7-Penta-O-methyl-d-glycero-l-manno-heptose was synthesized by methylationa of d-glycero-l-manno-heptose followed by hydrolysis. 2,4,6,7-Tetra-O-methyl-d-glycero-l-manno-heptose was synthesized by using the following sequence of reactions: 2-O-benzyl-d-galactose (7) → 3-O-benzyl-1-deoxy-1-nitro-d-glycero-l-manno-heptitol (8) → 3-O-benzyl-d-glycero-l-manno-heptose (9) → methyl 3-O-benzyl-2,4,6,7-tetra-O-methyl-d-glycero-l-manno-heptoside (10) → methyl 2,4,6,7-tetra-O-methyl-d-glycero-l-manno-heptoside (11) → 2,4,6,7-tetra-O-methyl-d-glycero-l-manno-heptose (12).
Publication date
LanguageEnglish
AffiliationNational Research Council Canada
Peer reviewedYes
NRC number11071
NPARC number21274549
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Record identifier6f67e240-6d32-4218-99ff-f63339623010
Record created2015-03-16
Record modified2016-05-09
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