Free radicals by mass spectrometry. V. The ionization potentials of methyl, allyl, and benzyl radicals

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DOIResolve DOI: http://doi.org/10.1063/1.1740136
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TypeArticle
Journal titleThe Journal of Chemical Physics
ISSN0021-9606
Volume22
Issue4
Pages621625; # of pages: 5
AbstractThe ionization potentials of methyl, allyl, and benzyl radicals have been measured directly by electron impact. The values found were methyl 9.95±0.03 ev, allyl 8,16±0.03 ev, and benzyl 7.73±0.08 ev. The radicals were produced by thermal decomposition of suitable compounds in a mass spectrometer designed for the study of free radicals. Reactions of the radicals after formation led to the expected dimers, but the disproportionation reactions were found to be negligibly slow.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC)
Peer reviewedYes
NPARC number21276766
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Record identifier6fa9badf-7406-4585-b814-1ac940d69741
Record created2015-10-13
Record modified2017-03-23
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