Temperature and site dependence of the rate of hydrogen and deuterium abstraction by methyl radicals in methanol glasses

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DOIResolve DOI: http://doi.org/10.1021/j150659a002
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TypeArticle
Journal titleThe Journal of Physical Chemistry
ISSN0022-3654
Volume88
Issue15
Pages31653167; # of pages: 3
AbstractRate constants are reported for hydrogen and deuterium abstraction by methyl radicals in CH3OH and CD3OD glasses in the ranges 5-89 and 77-97 K, respectively. At each temperature, they show a distribution due to a variation of radical trapping sites. The rate constants of this distribution are analyzed theoretically to yield a quantitative relation between tunneling rate and equilibrium tunneling distance.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC)
Peer reviewedYes
NPARC number21276639
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Record identifier731dbf9d-ab93-48e7-9cb3-36e586d58829
Record created2015-10-13
Record modified2017-03-23
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