Metal supported on dendronized magnetic nanoparticles: highly selective hydroformulation catalysts

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DOIResolve DOI: http://doi.org/10.1021/ja060140u
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TypeArticle
Journal titleJournal of the American Chemical Society
Volume128
Pages52795282; # of pages: 3
AbstractA method for homogenizing heterogeneous catalyst is described. The method is based on growing polyaminoamido (PAMAM) dendrons on silica-coated magnetic nanoparticles. After the dendronizing process, the silica-coated magnetic nanoparticles are more stable and more soluble in organic solvents. The dendronized particles are phosphonated, complexed with [Rh(COD)Cl]2, and applied in catalytic hydroformylation reactions. These new catalysts are proven to be highly selective and reactive.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC); NRC Institute for Chemical Process and Environmental Technology
Peer reviewedYes
NRC number52164
NPARC number16187134
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Record identifier73bc3453-93cb-4dd2-ab84-7fe319269b29
Record created2010-10-07
Record modified2016-05-09
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