Star polymers of sodium styrenesulfonate prepared by one-pot TEMPO-controlled SFRP

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DOIResolve DOI: http://doi.org/10.1071/CH12176
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TypeArticle
Journal titleAustralian Journal of Chemistry
ISSN0004-9425
Volume65
Issue8
Pages11171123; # of pages: 7
AbstractStar polymers of sodium styrenesulfonate with controlled arm length were prepared in a one-pot polymerization. Sodium styrenesulfonate was first polymerized with controlled molecular weight and narrow polydispersity by stable free radical polymerization. Poly(sodium styrenesulfonate) was terminated with divinyl benzene and star polymers prepared via stable free radical coupling of vinylic terminal groups. Star polymers based on arms of 20 and 32 repeat units possessed ~33 and ~41 arms per star respectively. Formation of star polymers with much longer arms was limited by poor coupling kinetics.
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LanguageEnglish
Peer reviewedYes
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NPARC number21269073
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Record identifier868459d7-b3ce-4845-8f7a-17f1b3d8b265
Record created2013-12-05
Record modified2016-05-09
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