Kinetic applications of electron paramagnetic resonance spectroscopy. 27. Isomerization of cyclopropylcarbinyl to allylcarbinyl

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DOIResolve DOI: http://doi.org/10.1021/ja00438a047
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TypeArticle
Journal titleJournal of the American Chemical Society
ISSN0002-7863
Volume98
Issue22
Pages70247026; # of pages: 3
AbstractThe rate constant for isomerization of cyclopropylcarbinyl to allylcarbinyl has been measured by EPR spectroscopy. It can be represented by: log(ki/s-1) = (12.48 ± 0.85) - (5.94 ± 0.57)/θ, where θ = 2.3RT kcal/mol. This reaction is compared with other primary alkyl radical isomerizations.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC)
Peer reviewedYes
NPARC number21276445
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Record identifier8976fe96-39b4-46bd-b7bc-78e46007e27d
Record created2015-10-13
Record modified2016-05-09
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