Thermally programmable gas storage and release in single crystals of an organic van der Waals host

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DOIResolve DOI: http://doi.org/10.1021/ja0351701
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TypeArticle
Journal titleJournal of the American Chemical Society
ISSN0002-7863
Volume125
Issue33
Pages98969897; # of pages: 2
AbstractA single crystal of a low density form of guest-free p-tert-butylcalix[4]arene can take up and release small guest molecules by controlling the temperature and pressure without changing the structure. Using NMR spectroscopy with flowing hyperpolarized xenon, we have shown that at room temperature access of xenon to the pore system is difficult, whereas it is relatively easy at 100 C. There are good prospects for simple van der Waals materials such as the title material to be used as programmable zeolite mimics.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
Identifier10072378
NPARC number12329010
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Record identifier8a682f60-4e90-4d9f-a35f-8c4843b4974c
Record created2009-09-10
Record modified2016-05-09
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