Infrared spectra of rare gas–carbon disulfide complexes: He–CS2, Ne–CS2, and Ar–CS2

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DOIResolve DOI: http://doi.org/10.1016/j.jms.2012.10.002
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TypeArticle
Journal titleJournal of Molecular Spectroscopy
ISSN00222852
Volume281
Pages2427
SubjectCarbon disulfide; Spectrum; Dimer; van der Waals; Infrared; Supersonic jet
AbstractSpectra of the weakly-bound van der Waals complexes Ar–CS2, Ne–CS2, and He–CS2 are studied in the region of the CS2ν3 fundamental band (≈1535 cm−¹) using a tunable diode laser to probe a pulsed supersonic expansion from a slit jet nozzle. He–CS2 is also observed in the ν1 + ν3 region (≈2185 cm−¹). These are the first reported spectra for rare gas–CS2 complexes, which are shown to have T-shaped structures similar to their CO2 analogs but with intermolecular separations which are 0.2–0.3 Å greater.
Publication date
LanguageEnglish
AffiliationSecurity and Disruptive Technologies; National Research Council Canada
Peer reviewedYes
IdentifierS0022285212001907
NPARC number21268791
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Record identifier8ce2da1f-51cd-4945-b74c-b08801bce7fc
Record created2013-11-13
Record modified2016-05-09
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