The lowest s Rydberg complex of CIF: c3Πi and C1Π

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DOIResolve DOI: http://doi.org/10.1016/0022-2852(83)90041-3
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TypeArticle
Journal titleJournal of Molecular Spectroscopy
ISSN0022-2852
Volume102
Issue2
Pages289296; # of pages: 8
AbstractThe absorption spectrum of CIF in the region 1400-1290 Å has been photographed at a dispersion of 0.18 Å/mm. The spectrum consists of bands degraded to shorter wavelengths and arises from transitions to the four components c3Π2, c3Π1, c3Π0, and C1Π1 of the first s Rydberg complex built on the X2Πi core of CIF+. Strong spin-orbit interactions distort the spin splitting of the triplet state and produce an unusual intensity distribution in the weak c3Π0 ← X1Σ+ transition. Upper state vibrational and rotational constants are given for the more abundant isotope 35CIF.
Publication date
LanguageEnglish
AffiliationNRC Herzberg Institute of Astrophysics; National Research Council Canada
Peer reviewedYes
NRC number122669
NPARC number21275097
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Record identifier90b180ed-012c-426c-bdb4-5bbcb30654f5
Record created2015-05-07
Record modified2016-05-09
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