Diethylamido- and pentafluorophenoxo-tungsten(VI) fluorides

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Journal titleJournal of the Chemical Society, Dalton Transactions
Pages18761879; # of pages: 4
AbstractTungsten hexafluoride reacts with trimethylsilyldiethylamine or trimethyl(pentafluorophenoxo)silane at or below ambient temperature with the replacement of F by –NEt2 or –OC6F5 groups. Compounds isolated were monomeric WF2(NEt2)4, polymeric WF4(NEt2)2 and monomeric WF5OC6F5. WF4(OC6F5)2 appears to exist in cis- and trans-forms and undergoes reorganisation to give other members of the series.
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NPARC number21270326
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Record identifier93a0bd43-ba1c-4e43-85c5-d85af9ecdbe3
Record created2014-01-24
Record modified2016-05-09
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