Describing chemical transformations in multiple spiking isotope dilution: fundamental aspects and definitions

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DOIResolve DOI: http://doi.org/10.1039/B814388A
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TypeArticle
Journal titleThe Analyst
ISSN0003-2654
1364-5528
Volume134
Issue3
Pages466471
AbstractCurrently, several mathematical methods exist to address simultaneous species formation and degradation using multiple spiking isotope dilution mass spectrometry. While all of these strategies have been compared numerically, comparison of the underlying principles is lacking. Owing to recent interest in using the species inter-conversion factors, mainly to study the quality of analytical methods, this manuscript reviews the mathematical logic and inconsistencies of the existing double or triple spiking isotope dilution models. Systematic terminology is also introduced to clarify the species inter-conversion coefficient definitions.
Publication date
PublisherRoyal Society of Chemistry
LanguageEnglish
AffiliationNRC Institute for National Measurement Standards; National Research Council Canada
Peer reviewedYes
NPARC number23001626
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Record identifier9952c5bc-d035-49e0-9b7a-fa4ed908c434
Record created2017-03-13
Record modified2017-03-13
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