Photoinduced alkyl group exchange of ethylzinc alkoxides: X-ray crystal structure of an iodomethylzinc methoxide

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DOIResolve DOI: http://doi.org/10.1039/b110736d
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TypeArticle
Journal titleChemical Communications
Issue5
Pages466467; # of pages: 2
AbstractIrradiation of a solution of ethyl zinc alkoxides and CH₂I₂ leads to clean formation of iodomethylzinc alkoxides; these intermediates are important species generated in stereoselective cyclopropanation processes; no alkyl group exchange is observed in the absence of irradiation; the solid-state structure of (MeO)₈Zn₇(CH₂I)₆ is also reported.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
NPARC number12329127
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Record identifiera03c4aab-3164-4728-92be-b7969c116296
Record created2009-09-10
Record modified2016-05-09
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