The initial product vibrational energy distribution in the reaction between O(1 D 2) and H2

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DOIResolve DOI: http://doi.org/10.1063/1.451230
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TypeArticle
Journal titleJournal of Chemical Physics
ISSN0021-9606
Volume85
Issue3
Pages14121417; # of pages: 6
SubjectFourier transform spectroscopy; hydrogen reactions; fourier transforms
AbstractWe report the first determination of the initial vibrational distribution in the OH product of the reaction between O(1 D 2) and H2. The measurement was made using a novel time-resolved Fourier transformspectroscopic technique which permits the observation of spectra on a microsecond time scale at a known time after the initiation of a reaction. The result is P(v’=1:2:3:4)=0.29:0.32:0.25:0.13 suggesting that the reaction dynamics involve very large attractive energy release during reagent approach followed by an extremely short-lived interaction leading to products within a few vibrational periods.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada
Peer reviewedYes
NRC number25667
NPARC number21275080
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Record identifieraad34e3f-933c-48ef-a12d-f0be51385ad7
Record created2015-05-07
Record modified2017-03-23
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