Mass bias fractionation laws for multi-collector ICPMS: assumptions and their experimental verification

Download
  1. (PDF, 650 KB)
  2. Get@NRC: Mass bias fractionation laws for multi-collector ICPMS: assumptions and their experimental verification (Opens in a new window)
DOIResolve DOI: http://doi.org/10.1021/ac9008435
AuthorSearch for: ; Search for: ; Search for: ; Search for:
TypeArticle
Journal titleAnalytical Chemistry
ISSN0003-2700
1520-6882
Volume81
Issue16
Pages67746778; # of pages: 5
AbstractAlthough mass bias fractionation correction is among the most studied theoretical aspects of analytical mass spectrometry, several assumptions imbedded in the conventional correction models remain largely untested. Experimental evidence is given herein highlighting parts-per-thousand deviations from the conventional mass bias correction models which can occur with use of multicollector inductively coupled plasma mass spectrometry. Furthermore, current mass spectrometric approaches are not capable of elucidating the fractionation exponent.
Publication date
LanguageEnglish
AffiliationNRC Institute for National Measurement Standards; National Research Council Canada
Peer reviewedYes
NPARC number21277193
Export citationExport as RIS
Report a correctionReport a correction
Record identifierabec0e70-99f4-4510-8d15-de8bfae96aba
Record created2016-01-05
Record modified2016-05-09
Bookmark and share
  • Share this page with Facebook (Opens in a new window)
  • Share this page with Twitter (Opens in a new window)
  • Share this page with Google+ (Opens in a new window)
  • Share this page with Delicious (Opens in a new window)