Synthesis and characterization of mixed ruthenium/platinum μ₄-phosphinidene, phosphorus monoxide, and related clusters

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DOIResolve DOI: http://doi.org/10.1021/ic0106423
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TypeArticle
Journal titleInorganic Chemistry
ISSN00201669
Volume40
Issue26
Pages67316736; # of pages: 6
AbstractThe mixed-metal cluster complexes [Ru4(CO)12Pt(CO)PPh3(4-PR)] [R = NiPr2 (1), F (3)] were formed by capping the Ru3P face of the nido clusters [Ru4(CO)13(3-PR)] with the labile Pt(0) reagent [(2-C2H4)Pt(PPh3)2]. The aminophosphinidene complex 1 undergoes acid hydrolysis to yield the PO complex [Ru4(CO)12Pt(CO)PPh3(4-PO)][H2NiPr2] (4). The fluorophosphinidene cluster 3 reacts with ethanol to form the alkoxyphosphinidene complex [Ru4(CO)12Pt(CO)PPh3(4-POEt)] (5). Comparison of spectroscopic and structural data for clusters 1, 3, 4, and 5 reveals the remarkable effects of the 4-phosphinidene and phosphorus monoxide ligands on cluster bonding.
Publication date
PublisherAmerican Chemical Society
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedYes
Identifier10007817
NPARC number12332907
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Record identifieraef23551-8d1a-4a77-9b26-45fa612bac39
Record created2009-09-10
Record modified2017-03-26
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