Terminal Aminophosphinidene Complexes of Iron, Ruthenium, and Osmium

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DOIResolve DOI: http://doi.org/10.1021/om030386x
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TypeArticle
Journal titleOrganometallics
ISSN0276-7333
Volume22
Issue19
Pages39273932; # of pages: 6
AbstractThe chloroaminophosphido complexes [Cp*M(CO)2{P(Cl)NiPr2}] (1, M = Fe; 2, M = Ru; 3, M = Os), formed by the reaction of [Cp*M(CO)2]- with iPr2NPCl2, undergo abstraction of chloride by aluminum trichloride, affording isolable, thermally stable, cationic terminal aminophosphinidene complexes [Cp*M(CO)2{PNiPr2}][AlCl4] (4, M = Fe; 5, M = Ru; 6, M = Os). The structures of all three complexes have been determined by single-crystal X-ray diffraction. The iron complex 4 has historical significance, having been spectroscopically detected at low temperature in 1984, prior to the description of the first stable 1-phosphinidene complex, but not isolated or structurally characterized.
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LanguageEnglish
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
Identifier10309731
NPARC number12327564
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Record identifierb311c75f-f498-4305-b91d-38222cf9f156
Record created2009-09-10
Record modified2016-05-09
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