Hydroformylation reactions with rhodium-complexed dendrimers on silica

Download
  1. (PDF, 226 KB)
  2. Get@NRC: Hydroformylation reactions with rhodium-complexed dendrimers on silica (Opens in a new window)
DOIResolve DOI: http://doi.org/10.1021/ja983764b
AuthorSearch for: ; Search for: ; Search for: ; Search for: ; Search for: ; Search for: ; Search for:
TypeArticle
Journal titleJACS: Journal of the American Chemical Society
Volume121
Issue13
Pages30353038; # of pages: 4
AbstractPolyamidoamine dendrimers, constructed on the surface of silica, were phosphonated by using diphenylphosphinomethanol, prepared in situ, and complexed to rhodium by use of [Rh(CO)₂Cl]₂. Excellent selectivities, favoring the branched aldehydes obtained from aryl olefins and vinyl esters, were observed by using the Rh(I) complex as the catalyst in hydroformylation reactions. The heterogeneous Rh (I) catalyst can also be recycled and reused without significant loss of selectivity or activity.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
NPARC number12340945
Export citationExport as RIS
Report a correctionReport a correction
Record identifierb8bd64ab-50a6-4265-b0ae-969332e9e3a7
Record created2009-09-11
Record modified2016-05-09
Bookmark and share
  • Share this page with Facebook (Opens in a new window)
  • Share this page with Twitter (Opens in a new window)
  • Share this page with Google+ (Opens in a new window)
  • Share this page with Delicious (Opens in a new window)