Multiple H 2 Occupancy of Cages of Clathrate Hydrate under Mild Conditions

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DOIResolve DOI: http://doi.org/10.1021/ja303222u
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TypeArticle
Journal titleJournal of the American Chemical Society
ISSN0002-7863
1520-5126
Volume134
Issue22
Pages91609162; # of pages: 3
AbstractExperiments were carried out by reacting H2 gas with N2 hydrate at a temperature of 243 K and a pressure of 15 MPa. The characterizations of the reaction products indicated that multiple H2 molecules can be loaded into both large and small cages of structure II clathrate hydrates. The realization of multiple H2 occupancy of hydrate cages under moderate conditions not only brings new insights into hydrogen clathrates but also refreshes the perspective of clathrate hydrates as hydrogen storage media.
Publication date
LanguageEnglish
AffiliationMeasurement Science and Standards; National Research Council Canada
Peer reviewedYes
NPARC number21269020
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Record identifierb9e3d0cf-feb3-41b4-b605-ca165c9f6031
Record created2013-12-02
Record modified2016-05-09
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