A Rod-Shaped Guest Leads to Architectural Isomerism in a Multicomponent Crystalline Framework Based on a Resorcin[4]arene

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DOIResolve DOI: http://doi.org/10.1021/cg0155245S1528-7483(01)05524-3
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TypeArticle
Journal titleCrystal growth & design
ISSN15287483
Volume1
Issue5
Pages373375; # of pages: 3
AbstractCocrystallization of C-methylcalix[4]resorcinarene 1 with 4,4'-bipyridine 2 in the presence of 4-bromobiphenyl (4-brbp) yields a molecular solid, of composition 3d?(4-brbp), [where 3d = 1?2(2)], in which 1 assembles with 2 to form a one-dimensional hydrogen-bonded polymer 3d that includes two copies of the biphenyl, within elliptical cavities of dimensions ~ 11 ? 7 ? 6 ?, as guests. The framework 3d represents a third architectural isomer of three previously reported supramolecular isomers of the parent material 3.
Publication date
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
Identifier18879068
NPARC number12329083
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Record identifierc74ba445-6266-4823-8557-438220d1521d
Record created2009-09-10
Record modified2016-05-09
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