Strain-promoted 1,3-dipolar cycloadditions of diazo compounds with cyclooctynes

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DOIResolve DOI: http://doi.org/10.1139/V10-112
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TypeArticle
Journal titleCanadian Journal of Chemistry
ISSN0008-4042
Volume89
Issue2
Pages148151; # of pages: 4
SubjectAnalogous reactions; Cycloadditions; Diazo compounds; Dibenzocyclooctyne; Dipolar cycloadditions; Nitrones; Second-order rate constants; Cycloaddition; Rate constants
AbstractStrain-promoted cycloadditions of diazo compounds with dibenzocyclooctyne proceed with second-order rate constants of >10 L mol -1s -1 at 25 °C. These reactions display rate constants that are comparable or greater than those of the analogous reactions of nitrones or azides with cyclooctynes.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC); NRC Steacie Institute for Molecular Sciences (SIMS-ISSM)
Peer reviewedYes
NPARC number21271133
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Record identifierce3813f3-e65f-42a3-b6a3-402798d85d37
Record created2014-03-24
Record modified2016-05-09
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