Rate of reaction of phenyl radicals with oxygen in solution and in the gas phase

Download
  1. Get@NRC: Rate of reaction of phenyl radicals with oxygen in solution and in the gas phase (Opens in a new window)
DOIResolve DOI: http://doi.org/10.1021/j100134a001
AuthorSearch for: ; Search for: ; Search for: ; Search for: ; Search for: ; Search for:
TypeArticle
Journal titleJournal of Physical Chemistry
ISSN0022-3654
Volume97
Issue32
Pages83618364; # of pages: 4
AbstractThe rate constant for the title reaction, k1, is 3.8 × 109 M-1 s-1 in water at 298 K and is ≥ 108 M-1 s-1 in the gas phase at 603 K. It is concluded that two reports8,11 that this reaction is very slow in the gas phase, k1 ≤ 1.2 × 104 and ∼2.3 × 106 M-1 s-1, are in error. © Copyright 1993 by the American Chemical Society.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC); NRC Steacie Institute for Molecular Sciences (SIMS-ISSM)
Peer reviewedYes
NPARC number21276772
Export citationExport as RIS
Report a correctionReport a correction
Record identifierd5a3b16d-25f9-41de-9ff3-e8495cce533d
Record created2015-10-13
Record modified2016-05-09
Bookmark and share
  • Share this page with Facebook (Opens in a new window)
  • Share this page with Twitter (Opens in a new window)
  • Share this page with Google+ (Opens in a new window)
  • Share this page with Delicious (Opens in a new window)