Surface chemistry of gold nanoparticles produced by laser ablation in aqueous media

DOIResolve DOI: http://doi.org/10.1021/jp047134+
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TypeArticle
Volume108
Issue43
Pages1686416869; # of pages: 6
Subjectchemistry; env; Solutions; analysis; Oxygen; Water
AbstractThe femtosecond laser ablation of a gold target in aqueous solutions has been used to produce colloidal Au nanoparticles with controlled surface chemistry. A detailed chemical analysis showed that the nanoparticles formed were partially oxidized by the oxygen present in solution. The hydroxylation of these Au-O compounds, followed by a proton loss to give surface Au-O-, resulted in the negative charging of the nanoparticles. The partial oxidation of the gold nanoparticle surface enhances its chemical reactivity and consequently has a strong impact on its growth. In particular, the oxidized surface reacted efficiently with Cl- and OH- to augment its net surface charge. This limited the coalescence of the particles, due to electrostatic repulsion, and led to a significant reduction of their size. Taking advantage of the repulsion effect, efficient size control was achieved using different salts (7 � 5 nm for 10 mM KCl, 5.5 � 4 nm for 10 mM NaCl, 8 � 5 nm for NaOH, pH 9.4), a considerable improvement comparatively to particles prepared in deionized water, using identical ablation conditions, where particles of 1-250 nm were produced. The partially oxidized gold surface was also suitable for surface modification through both covalent and electrostatic interactions during particle formation. Using solutions of N-propylamine, we showed an efficient control of nanoparticle size (5-8 � 4-7 nm) by the involvement of these interactions. The results obtained help to develop methodologies for the control of laser-ablation-based nanoparticle growth and the functionalization of nanoparticle surfaces by specific interactions.
Publication date
AffiliationNRC Biotechnology Research Institute; National Research Council Canada
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Peer reviewedNo
NRC number47210
NPARC number3539286
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Record identifiere36b2af7-a423-4368-81a2-c6d5478edfc3
Record created2009-03-01
Record modified2016-05-09
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