Absolute rate constants for the decarbonylation of the phenylacetyl radical

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DOIResolve DOI: http://doi.org/10.1021/j100227a001
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TypeArticle
Journal titleThe Journal of Physical Chemistry
ISSN0022-3654
Volume87
Issue4
Pages529530; # of pages: 2
AbstractThe rate of α scission of the phenylacetyl radical has been determined by laser flash photolysis in isooctane, methanol, and tetrahydrofuran. There is no significant solvent effect on the rate. In isooctane, the rate constant for decarbonylation can be represented by log (k/s-1) = (12.0 ± 0.3) - (6.9 ± 0.4)/2.3RT kcal/mol. © Copyright, 1983, by the American Chemical Society.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC)
Peer reviewedYes
NPARC number21276462
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Record identifiere89bf005-3fe4-4f98-b9c6-0dc4c6be91de
Record created2015-10-13
Record modified2017-03-23
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