Chasmanine and its structure

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DOIResolve DOI: http://doi.org/10.1139/v65-110
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TypeArticle
Journal titleCanadian Journal of Chemistry
ISSN0008-4042
Volume43
Issue4
Pages825839; # of pages: 15
AbstractThe alkaloid chasmanine, C25H41O6N, isolated from A. chasmanthum contains four methoxyl and two hydroxyl groups as well as an imino-ethyl. It undergoes the usual pyrolytic reaction and the unsaturated product, pyrochasmanine, C25H39O5N, gives rise to an acid-catalyzed allylic rearrangement product, isopyrochasmanine. Pyrochasmanine, on treatment with lithium aluminium hydride, is demethoxylated. ...
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LanguageEnglish
AffiliationNational Research Council Canada
Peer reviewedYes
NPARC number21274426
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Record identifierf5baf1e2-15b6-441c-8e10-66ebabd08134
Record created2015-03-12
Record modified2016-05-09
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