Perfluoro-tert-butyl, a reactive, neutral, electrophilic carbon-centered radical par excellence

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DOIResolve DOI: http://doi.org/10.1016/0040-4020(96)00742-9
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TypeArticle
Journal titleTetrahedron
ISSN0040-4020
Volume52
Issue38
Pages1235112356; # of pages: 6
Subjectalkene derivative; article; chemical reaction kinetics; drug synthesis; priority journal; reaction analysis; technique
AbstractAbsolute rate constants for (CF3)3C. addition to terminal olefins increase by roughly a factor of 30 for every 1 eV decrease in the ionization potential (IP) of the alkene. A similar decrease in IP increases the rate of addition of CF3. and n-C3F7. by a factor of only 3 or 4. The perfluoro-tert-butyl radical is, therefore, the most electrophilic, neutral carbon-centered radical to have been studied to date.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC)
Peer reviewedYes
NPARC number21276492
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Record identifierf5d9de9f-8294-404b-b2bc-6f17d77ba88a
Record created2015-10-13
Record modified2016-05-09
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