Identification of volatile iron species generated by UV photolysis

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DOIResolve DOI: http://doi.org/10.1016/j.microc.2012.05.036
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TypeArticle
Journal titleMicrochemical Journal
ISSN0026-265X
Volume105
Pages4447; # of pages: 4
Subjectvolatile metal species; vapor generation; iron; iron pentacarbonyl; GC-MS; silylation
AbstractThe volatile products of photochemical generation (PVG) of iron from solutions of formic and acetic acids were examined by GC-MS. Iron pentacarbonyl was the sole analytical species detected in both cases, as confirmed by comparison of the results with a NIST reference spectrum. Silylation of the interior surfaces of the quartz tubing comprising the photochemical reactor essentially eliminated memory effects such that signal duration was determined simply by the residence time of the sample solution.
Publication date
PublisherElsevier
LanguageEnglish
AffiliationMeasurement Science and Standards; National Research Council Canada
Peer reviewedYes
NRC numberMICROC 1591
NPARC number20951807
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Record identifierf69e7613-d062-444d-88a2-0a3e7f057154
Record created2012-11-13
Record modified2016-05-09
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