Bound-free gas transport coefficients via the time correlation formulation based on an atomic picture

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DOIResolve DOI: http://doi.org/10.1063/1.478761
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TypeArticle
Journal titleThe Journal Of Chemical Physics
Volume110
Issue17
Pages85338542; # of pages: 10
SubjectBoltzmann equation; transport processes
AbstractThe values of gas transport coefficients, when both unbound particles and bound pairs are present, are standardly accounted for by treating the gas as a mixture of free atoms and bound pairs and using the well-known expressions for the transport coefficients for a mixture. But since the bound pairs consist of two atoms, it should also be possible to start from a purely atomic picture of the gas. This paper accomplishes that aim, starting with the time correlation function expression for the transport coefficient in terms of atomic variables.
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LanguageEnglish
Peer reviewedNo
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This is a non-NRC publication

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NPARC number12333648
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Record identifierf95a7827-ab95-4bb3-9922-3451fff6a0e5
Record created2009-09-10
Record modified2017-03-23
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